Born and raised in Florence, Alessandra has a degree in art history from the University of Florence with a specialization in seventeenth-century painting. She obtained an Masters from the European University Institute in Florence, where she defended her Ph.D. in history, focusing on the patronage of Tuscan nobility in Europe during the seventeenth century. In addition, she holds a diploma in archival administration, paleography, and diplomatics from the State Archive in Florence. She has been teaching art history and Italian culture for several years in various schools and institutions in Florence and across Italy.